Wednesday, May 11, 2011

Historical background

The first observations and size measurements of nano-particles was made during the first decade of the 20th century. They are mostly associated with Richard Adolf Zsigmondy who made a detailed study of gold sols and other nanomaterials with sizes down to 10 nm and less. He published a book in 1914.[1] He used ultramicroscope that employes the dark field method for seeing particles with sizes much less than light wavelength. Zsigmondy was also the first who used the term nanometer explicitly for characterizing particle size. He determined it as 1/1,000,000 of millimeter. He developed the first system classification based on particle size in the nanometer range.

There have been many significant developments during the 20th century in characterizing nanomaterials and related phenomena, belonging to the field of interface and colloid science. In the 1920s, Irving Langmuir and Katharine B. Blodgett introduced the concept of a monolayer, a layer of material one molecule thick. Langmuir won a Nobel Prize in chemistry for his work. In the early 1950s, Derjaguin and Abrikosova conducted the first measurement of surface forces.[2]

There have been many studies of periodic colloidal structures and principles of molecular self-assembly that are overviewed in the paper.[3] There are many other discoveries that serve as the scientific basis for the modern nanotechnology which can be found in the "Fundamentals of Interface and Colloid Science by H.Lyklema.[4]

In 1965 Gordon Moore observed that silicon transistors were undergoing a continual process of scaling downward, an observation which was later codified as Moore's law. Since his observation transistor minimum feature sizes have decreased from 10 micrometers to the 45-65 nm range in 2007; one minimum feature is thus roughly 180 silicon atoms long.

Also in 1974 the process of atomic layer deposition, for depositing uniform thin films one atomic layer at a time, was developed and patented by Dr. Tuomo Suntola and co-workers in Finland.

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